2. Heavy metals in the Adriatic-Ionian Seas : a case study to illustrate the challenges in data management when dealing with regional datasetsMaria-Eugenia Molina Jack, Rigers Bakiu, Ana Castelli, Branko Čermelj, Maja Fafanđel, Christina Georgopoulou, Giordano Giorgi, Athanassia Iona, Damir Ivankovic, Martina Kralj, Elena Partescano, Alice Rotini, Melita Velikonja, Marina Lipizer, 2020, izvirni znanstveni članek Povzetek: Harmonization of monitoring protocols and analytical methods is a crucial issue for transnational marine environmental status assessment, yet not the only one. Coherent data management and quality control become very relevant when environmental status is assessed at regional or subregional scale (e.g., for the Mediterranean or the Adriatic Sea), thus requiring data from different sources. Heavy metals are among the main targets of monitoring activities. Significant efforts have been dedicated to share best practices for monitoring and assessment of ecosystem status and to strengthen the network of national, regional and European large data infrastructures in order to facilitate the access to data among countries. Data comparability and interoperability depend not only on sampling and analytical protocols but also on how data and metadata are managed, quality controlled and made accessible. Interoperability is guaranteed by using common metadata and data formats, and standard vocabularies to assure homogeneous syntax and semantics. Data management of contaminants is complex and challenging due to the high number of information required on sampling and analytical procedures, high heterogeneity in matrix characteristics, but also to the large and increasing number of pollutants. Procedures for quality control on heterogeneous datasets provided by multiple sources are not yet uniform and consolidated. Additional knowledge and reliable long time-series of data are needed to evaluate typical ranges of contaminant concentration. The analysis of a coherent and harmonized regional dataset can provide the basis for a multi-step quality control procedure, which can be further improved as knowledge increases during data validation process.
Ključne besede: contaminants, data management, harmonization, Adriatic Sea, Ionian Sea, pollution, assessment, heavy metals
Objavljeno v DiRROS: 22.07.2024; Ogledov: 1314; Prenosov: 722
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3. Challenges in harmonized assessment of heavy metals in the Adriatic and Ionian SeasDaniela Berto, Margherita Malgorzata Formalewicz, Giordano Giorgi, Federico Rampazzo, Claudia Gion, Benedetta Trabucco, Michele Giani, Marina Lipizer, Slavica Matijević, Helen Kaberi, Christina Zeri, Oliver Bajt, Nevenka Mikac, Danijela Joksimović, Andriana Aravantinou, Mateja Poje, Magdalena Cara, Loredana Manfra, 2020, izvirni znanstveni članek Povzetek: The Adriatic-Ionian region (ADRION Region) shows strong development in terms of urban expansion in coastal and inland areas as well as increasing maritime traffic and offshore hydrocarbon extraction activities. A serious risk of pollution arises from hazardous substances requiring reliable and coherent monitoring and assessment programs. EU Directives (WFD – Water Framework Directive, MSFD – Marine Strategy Framework Directive) and Barcelona Convention protocols, aim to assess the level of pollution with the objective to implement measures to prevent and/or mitigate impacts on the marine environment. This high level integration process has to be based on common and agreed protocols for monitoring of contaminants. Aiming to share best practices to encourage a harmonized implementation of monitoring and assessment of contaminants, an extensive review of monitoring and analytical protocols adopted by six EU and non-EU countries along the Adriatic and Ionian seas was carried out in the framework of the Interreg Adrion project HarmoNIA (Interreg V-B Adriatic-Ionian (ADRION), 2018–2020). This paper presents a methodological proposal to define a common protocol for the evaluation of the metal contamination of seawater, sediment and biota. Contaminants have been chosen following preliminary consultations among countries of the ADRION area, considering objectives of WFD and MSFD, as well as Environmental Impact Assessment (EIA) procedures for offshore platforms. Information was gathered relative to matrix characteristics and quality assurance/quality control of the analytical performance (sample preservation, analytical methodology, reference materials, limit of detection, and limit of quantification, accuracy, reproducibility, etc.). The comparison of information provided by laboratories of nine institutions highlighted the request for harmonization in terms of sampling procedures, matrix characterization, preservation procedures, analytical methods and LOQ values. Although appropriate environmental quality standards for biota and sediment matrices should be established at national level and also through regional and sub-regional cooperation, as required by the WFD and MSFD, the proposed LOQ values, even if challenging, represent a benchmark and a stimulus to optimize analytical performance, to ensure the best level of protection to the coastal and offshore environment in the ADRION Region.
Ključne besede: hazardous substances, harmonized protocols, integrated approach, monitoring, assessment of contaminants, heavy metals, Adriatic-Ionian Sea region
Objavljeno v DiRROS: 22.07.2024; Ogledov: 1300; Prenosov: 687
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