1. Stabilization of river dredged sediments by means of alkali activation technologyKarmen Fifer Bizjak, Lea Žibret, Mojca Božič, Boštjan Gregorc, Vilma Ducman, 2024, izvirni znanstveni članek Povzetek: Purpose
Alkali activation process has been applied to fresh river clay-rich sediments in order to increase their mechanical properties and make them suitable for soil stabilization.
Materials and methods
Dredged sediments were mixed with up to 30 mass percent (ma%) of fly ash (FA) or ladle slag (LS) and after curing for 3 days at 60 °C, the bending and compressive strength have been determined. The mixtures which exhibited the highest strengths were further optimized for being used in soil stabilization. For this purpose, the sediment was stabilized with 4 ma% of quicklime (QL) and after 1 h 30 ma% of FA with alkali activator was added and cured for 1, 7 and 28 days.
Results
The stabilized sediment has a significantely better geomechanical performance in comparison with the sediment alone. Stabilizing the dredged sediment using alkali activation technology provides high enough strengths to eventually make it suitable for anti-flood embankments.
Conclusions
The results confirmed the suitability of the investigated technology for soil stabilization.
Ključne besede: river sediment, alkali activated materials, ladle slag, fly ash, mechanical strength, soil stabilization
Objavljeno v DiRROS: 09.09.2024; Ogledov: 190; Prenosov: 4643
 Celotno besedilo (1,41 MB)
Gradivo ima več datotek! Več... |
2. Optimizing process parameters of clay-based ceramics with addition of construction and demolition wasteBiljana Angjusheva, Vilma Ducman, Monika Fidancevska, Vojo Jovanov, 2021, izvirni znanstveni članek Povzetek: Construction and demolition waste produced in the Republic of North Macedonia remains a major economic and environmental problem because all construction and demolition waste ends up in local dumps or is disposed of in a landfill. The objective of this study was to investigate the influence of the process parameters on the physical and mechanical properties of clay-based ceramics with partial replacement of clay with construction and demolition waste. Determination of the chemical composition of the waste demolition brick using X-ray fluorescence showed that it consisted of different oxides such as SiO2, Al2O3, Fe2O3 and CaO and minor contents of alkaline and earth alkaline oxides. Production of these ceramics was conducted through the consolidation of clay and waste demolition brick with the evaluation of the main process parameters such as sintering temperature [ST], the content of waste demolition brick [WDB] and isothermal period at the final temperature [IP]. The final model equations for density and bending strength dependence of the main process parameters were obtained and presented. The microstructure of the ceramics determined by SEM shows that the waste material is homogeneously dispersed in the clay matrix.
Ključne besede: CDW, clay, ceramics, properties
Objavljeno v DiRROS: 19.08.2024; Ogledov: 266; Prenosov: 120
Celotno besedilo (884,49 KB)
Gradivo ima več datotek! Več... |
3. Lightweight aggregates made from fly ash using the cold-bond process and their use in lightweight concreteAna Frankovič, Violeta Bokan-Bosiljkov, Vilma Ducman, 2017, izvirni znanstveni članek Povzetek: Aggregates made from fly ash have been developed by means of the cold-bonding process, with the addition of Portland cement as a binder at (10, 20, and 30) % of mass fractions, and by pouring the mixtures into moulds. After curing for 28 d the samples were processed into aggregate by crushing and sieving. An aggregate containing a weight percentage of 10 % of cement was additionally produced by pelletization on a granulating plate. The density, water-adsorption capacity, porosity, compressive strengths, and frost resistance of the samples were determined. The aggregates prepared by both routes were then used to make concrete samples, whose properties were then compared to those of conventional concrete made using limestone aggregate. The compressive strength of the concrete made with the granulated aggregate reached 16.0 MPa after 28 d, whereas that of the concrete made with crushed aggregate amounted to 24.1 MPa, and that of the conventional concrete was 34.6 MPa.
Ključne besede: fly ash, lightweight aggregates, density, compressive strength, frost resistance
Objavljeno v DiRROS: 14.08.2024; Ogledov: 286; Prenosov: 204
Celotno besedilo (1,65 MB)
Gradivo ima več datotek! Več... |
4. An evaluation of marine sediments in terms of their usability in the brick industry : case study Port of KoperPatrik Baksa, Franka Cepak, Rebeka Kovačič Lukman, Vilma Ducman, 2018, izvirni znanstveni članek Povzetek: A dredging process is essential for the development of harbours and ports, allowing the functional daily operation of the port. The management of dredged material represents a worldwide challenge, especially considering unwanted deposition of material. Because of their chemical, petrographic, mineralogical and homogeneity composition, marine sediments could represent an appropriate raw material for the brick industry, particularly for the production of clay blocks, roofing and ceramic tiles. In this study dredged material from Port of Koper was tested for such use, thus various analyses were carried out in order to determine if the dredged material is environmentally friendly and suitable for use in the brick industry. These included: chemical analysis, mineralogical analysis, particle size analysis, chloride content analysis and tests of firing in a gradient furnace. Furthermore, tests of mechanical properties, as well as tests of the frost-resistance of the samples were carried out. On the basis of the primary analyses and samples prepared in a laboratory, it was confirmed that marine sediments from the Port of Koper, without any additives are only conditionally suitable as a source material for producing brick products, because without additives they exhibit too much shrinkage on drying and firing, as well as high water absorption, this can be improved by the incorporation of suitable additives, for example, virgin clay or other suitable waste material. The approach described herewith can also be followed to assess sediments from other ports and rivers regarding its potential use in clay brick sector.
Ključne besede: dredge marine sediment, recycling, clay bricks, mechanical properties, chemical analysis
Objavljeno v DiRROS: 14.08.2024; Ogledov: 255; Prenosov: 142
Celotno besedilo (448,54 KB)
Gradivo ima več datotek! Več... |
5. Increasing the amorphous content in river sediments intended for supplementary cementitious materials using flame synthesisWolfgang Wisniewski, Jozef Kraxner, Lea Žibret, Dušan Galusek, Vilma Ducman, 2024, izvirni znanstveni članek Povzetek: Dredged river sediments are currently a waste material which is mainly landfilled or reintegrated into rivers. They can also be used as a renewable resource for the construction sector. Pre- treatments at high temperatures allow their use for more advanced applications such as supplementary cementitious materials (SCMs) or as a precursor for alkali activated materials (AAMs). The work presented here shows that flame synthesis can be used to almost completely vitrify such sediments and increase their leachability for Al and Si beyond the levels achieved by conventional calcination at 750–950 ◦C for 1h.
The reactivity of the prepared samples was analyzed via the Si and Al solubility in 10 M NaOH and was generally increased by the applied treatments but maximized by flame synthesis. Their microstructure was analyzed using scanning electron microscopy and their phase composition was monitored using X-ray diffraction. The results show an almost complete amorphization of the sediments by flame synthesis, however their reactivity does not increase at the same rate.
Ključne besede: sediments, SCM, vitrification, properties
Objavljeno v DiRROS: 23.05.2024; Ogledov: 408; Prenosov: 297
Celotno besedilo (2,50 MB)
Gradivo ima več datotek! Več... |
6. Why geopolymers and alkali-activated materials are key components of a sustainable world : a perspective contributionWaltraud M. Kriven, Cristina Leonelli, John L. Provis, Aldo R. Boccaccini, Cyril Attwell, Vilma Ducman, Claudio Ferone, Sylvie Rossignol, Tero Luukkonen, Jannie S. J. Van Deventer, José V. Emiliano, Jérôme E. Lombardi, 2024, izvirni znanstveni članek Povzetek: This perspective article delves into the transformative potential of alkali-activated materials, acid-activated materials, and geopolymers in mitigating climate change and market challenges. To harness the benefits of these materials, a comprehensive strategy is proposed. This strategy aims to integrate these materials into existing construction regulations, facilitate certification, and promote market access. Emphasizing research and innovation, the article advocates for, increased funding to refine the chemistry and production of these materials, prioritizing low-cost alternatives and local waste materials. Collaboration between academia and industry is encouraged to expedite technological advances and broaden applications. This article also underscores the need to develop economic and business models emphasizing the long-term benefits of these materials, including lower life-cycle costs and reduced environmental impact. Incentivizing adoption through financial mechanisms like tax credits and subsidies is suggested. The strategy also includes scaling up production technology, fostering industrial collaboration for commercial viability, and developing global supply chains. Educational programs for professionals and regulators are recommended to enhance awareness and adoption. Additionally, comprehensive life-cycle assessments are proposed to demonstrate environmental benefits. The strategy culminates in expanding the applications of these materials beyond construction, fostering international collaboration for knowledge sharing, and thus positioning these materials as essential for sustainable construction and climate change mitigation.
Ključne besede: geopolymers, alkali activated materials, perspective
Objavljeno v DiRROS: 15.04.2024; Ogledov: 438; Prenosov: 454
Celotno besedilo (1,63 MB)
Gradivo ima več datotek! Več... |
7. Characterization and Mechanical Properties of Sintered Clay MineralsSara Tominc, Vilma Ducman, Jakob Koenig, Srečo D. Škapin, Matjaž Spreitzer, 2024, objavljeni znanstveni prispevek na konferenci Povzetek: The need to reduce energy consumption and the carbon footprint generated by firing ceramics has stimulated research to develop sintering processes carried out at lower temperatures(ideally not above 300 °C) and high pressures (up to 600 MPa), the so-called cold sintering process (CSP) (Grasso et al., 2020, Maria et al., 2017). To evaluate the applicability of CSP to clays, we focused on two representative clay minerals, kaolinite and illite, and on the natural clay material obtained from a Slovenian brick manufacturer. The selected clay materials were characterized on the basis of mineralogical-chemical composition (XRD, XRF) and particle size distribution (SEM analysis, PSD, BET). The powders of clay minerals and natural clay material were first sintered in a heating microscope to determine the sintering conditions and then in a laboratory furnace at 1100 °C for 2 hours and additionally at 1300 °C for kaolinites. The effect of compression of the initial powders on their final properties was also investigated.
Ključne besede: conventional sintering, cold sintering, clay minerals, characterization, mechanical properties
Objavljeno v DiRROS: 29.03.2024; Ogledov: 482; Prenosov: 224
Celotno besedilo (681,81 KB)
Gradivo ima več datotek! Več... |
8. Innovative pre-fabricated components including different waste construction materials reducing building energy and minimising environmental impacts (InnoWEE)Elena Loredana Fodor, Vilma Ducman, Giovanni Ferrarini, Sergio Tamburini, Constantinos Tsoutis, Francesca Becherini, Antonio Garrido-Marijuán,, Giulia Mezzasalma, Leonardo Rossi, Emil Lezak, Adriana Bernardi, 2019, objavljeni znanstveni prispevek na konferenci Povzetek: InnoWEE is a four-year project (from 2016 to 2020) financed by the European Community that involves ten partners from different European countries, as Greece, Italy, Belgium, Romania, Slovenia, Spain and Poland. The aim is to use the waste materials coming from construction and demolition processes of buildings and include them into a geopolymeric matrix with the purpose of producing prefabricated panels for different applications. Construction and demolition waste (CDW) materials with suitable characteristics have been selected to develop high performance geopolymeric panels for building walls envelopes and radiant panels for indoor walls and ceilings with low environmental impact. Field tests will be carried out in different sites in Europe characterized by different climatic conditions to check the simplicity of the installation procedure and the performance of the panels in terms of energy efficiency and environmental impact.
Ključne besede: prefabriced elements, geopolymers, CDW
Objavljeno v DiRROS: 08.03.2024; Ogledov: 410; Prenosov: 195
Celotno besedilo (1,99 MB)
Gradivo ima več datotek! Več... |
9. Evaluation of fly ash-based alkali activated foams at room and elevated temperaturesKatja Traven, Mark Češnovar, Srečo D. Škapin, Vilma Ducman, 2020, objavljeni znanstveni prispevek na konferenci Povzetek: Alkali activated materials (AAM) are, in their broadest classification, any binder systems derived by the reaction of an alkali metal source (silicates, alkali hydroxides, carbonates , sulphates) with a solid, amorphous alumosilicate powder (found in precursors such as slag, fly ash and bottom ash). A wide variety of products can be obtained by the alkali activation process and could replace traditional construction products. Among the se, alkali activated foams (AAF) represent one of the most promising materials, owing to their economically accessible alumosilicate rich source materials, including industrial waste materials, clean processing, higher added value and most importantly, pro ducts with competitive properties. In the present study, the properties of alkali activated fly ash - based foam materials were studied at room temperature as well as at elevated temperatures (up to 1200 °C ) in order to develop a durable material in terms o f mechanical properties and suitability for high temperature applications.
Ključne besede: lightweight porous insulating material, alkali activated materials, microstructural analysis
Objavljeno v DiRROS: 05.03.2024; Ogledov: 560; Prenosov: 423
Celotno besedilo (970,74 KB)
Gradivo ima več datotek! Več... |
10. Foundry wastes as a potential precursor in alkali activation technologyBarbara Horvat, Alenka Sešek Pavlin, Vilma Ducman, 2020, objavljeni znanstveni prispevek na konferenci Povzetek: In this study the amount of amorphous phase of elements useful in alkali activation of waste materials produced by the foundry industry was determined. Waste foundry sands, foundry flue gas and waste casting cores were alkali activated, and waste green ceramics and bottom ash were added to one of the foundry sand samples to shorten the time for producing measurable compressive strength from 1.5 years to 1 week.
Ključne besede: alkali activated materials, foundry wastes, compressive strength, upcycling, circular ecnomy
Objavljeno v DiRROS: 01.03.2024; Ogledov: 424; Prenosov: 330
 Povezava na datoteko
Gradivo ima več datotek! Več... |
