1. Shooting activities as the potential influence on the environment at the Pokljuka biathlon center, SloveniaValentina Pezdir, Mateja Gosar, 2025, izvirni znanstveni članek Povzetek: Biathlon activities can have negative effects on the environment due to the processes occurring during shooting, as the biathlon ammunition contains significant amounts of Pb, Cu and Sb. To determine these effects, we looked into the presence of lead-bearing particles in the vicinity of a shooting range in Rudno polje, Pokljuka, in Slovenia. Particles were collected from snow and later analysed using SEM/EDS, where we focused on the lead-bearing particles. These particles are composed of mainly lead or lead oxides/hydroxides with trace presence of Cu and Sb, both of which are commonly related to ammunition used in biathlon shooting and other shooting activities. To confirm that the particles originated from shooting, we compared them with particles taken from an indoor shooting range as dust and residue in ammunition casings. Lead-bearing particles show morphological changes that are caused by high temperatures and pressures during the shooting process. Ključne besede: atmospheric particles, ammunition residue, SEM/EDS Objavljeno v DiRROS: 03.09.2025; Ogledov: 783; Prenosov: 191
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2. Evaluating mineral matter dynamics within the peatland as reflected in water compositionValentina Pezdir, Luka Serianz, Mateja Gosar, 2024, izvirni znanstveni članek Povzetek: Peatland hydrology plays an important role in preserving or changing the record in any consideration of past atmospheric deposition records in peat bogs. The Šijec bog, located on the Pokljuka plateau in Slovenia, is one of the largest ombrotrophic peatlands. We sampled the surface pools, pore water, drainage from the peatland, and karst streams not connected to the peatland. Additionally, we sampled the precipitation, as ombrotrophic peatlands receive mineral matter solely from the atmosphere. The results of the evaluation of the chemical and isotopic composition indicated different origins of dissolved mineral matter in different water types. The components originating from the bedrock and surrounding soils (Ca, Mg, Al, Si, Sr) predominated in the streams. The chemical composition of the peatland drainage water revealed the significant removal of major components from the peatland, particularly elements like Al, Fe, and REE, and metals that are readily dissolved in an acidic environment or mobile in their reduced state. Despite their solubility, concentrations of metals (As, Cr, Cu, Fe, Ni, Pb, Ti) and REE in surface pools remained higher than in the drainage due to incomplete elimination from the peatland. The composition of pore water reflects variations among the W and E parts of the peatland, indicating a heterogenous hydrological structure with different dynamics, such as an additional source of water at approximately 90 cm depth in the NW part. The chemical composition and isotope signature (18O and 2H) of pore water additionally indicated a heterogeneous recharge with residence times of less than a year. The overall analysis indicated a predominantly ombrotrophic type and a small part in the NW area of the peatland as a minerotrophic type of peat. Ključne besede: peatland, hydrogeochemistry, isotopes Objavljeno v DiRROS: 18.06.2024; Ogledov: 1133; Prenosov: 453
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3. Characterization of atmospheric deposition as the only mineral matter input to ombrotrophic bogValentina Pezdir, Martin Gaberšek, Mateja Gosar, 2022, izvirni znanstveni članek Povzetek: Ombrotrophic peatlands contain a very small percentage of mineral matter that they receive exclusively from atmospheric deposition. Mineral matter deposited on the Šijec bog was characterized using scanning electron microscopy coupled with energy dispersive spectroscopy (SEM/EDS). We collected solid atmospheric deposition from snow, rainwater, and using passive samplers. Samples were collected at average atmospheric conditions and after two dust events. Size, morphology, and chemical composition of individual particles were determined. We distinguished four main particle groups: silicates, carbonates, organic particles, and Fe-oxyhydroxides. Silicate particles are further divided into quartz and aluminosilicates. Proportions of these groups vary between samples and between sample types. In all samples, silicate particles predominate. Samples affected by dust events are richer in solid particles. This is well observed in passive deposition samples. Carbonates and organic particles represent smaller fractions and are probably of local origin. Iron-oxyhydroxides make up a smaller, but significant part of particles and are, according to their shape and chemical composition, of both geogenic and anthropogenic origin. Estimated quantity and percentage of main groups vary throughout the year and are highly dependent on weather conditions. Dust events represent periods of increased deposition and contribute significantly to mineral matter input to peatlands. Ključne besede: atmospheric deposition, SEM/EDS, mineral matter, peatland Objavljeno v DiRROS: 08.09.2022; Ogledov: 2262; Prenosov: 941
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4. Investigating peatland stratigraphy and development of the Šijec bog (Slovenia) using near-surface geophysical methodsValentina Pezdir, Teja Čeru, Barbara Horn, Mateja Gosar, 2021, izvirni znanstveni članek Povzetek: Owing to their anoxic environment, peatlands play an important role in the preservation of records documenting past atmospheric depositions. To determine past records, data on peat stratigraphy and bog development are needed. Ground penetrating radar (GPR) was used to determine the peat thickness and morphology of the Šijec bog on the Pokljuka plateau in Slovenia, which will serve as a basis for further geochemical studies. Information on the stratigraphy below the peat/clay boundary was acquired by applying electrical resistivity tomography (ERT). The GPR results reveal four depressions within the peat bog, which are separated by elevated ridges. Within the depressions the peat reaches a depth of 6–9 m. The edges of the bog are flat, with peat thickness ranging from 2 to 4 m. The reach of the GPR was complemented with manual peat probing. A comparison of the depths obtained using GPR and the peat probe reveals that the results of both methods correspond well in most locations. The ERT indicated similar peat depths; peat responds with high electrical resistivity. In contrast, clayey sediments with low resistivity are found below the peat. The peat depressions are underlain with larger clayey depressions reaching more than 20 m in thickness and represent lake sediments. The complementary geophysical methods proved to be an efficient approach with which we can delineate the peat morphology and the underlying stratigraphy. Both indicate bog formation from a lake with four deeper depressions, that are separated by glacial deposits. The results presented here show the potential for geophysical methods to infer formational processes in peatlands, showing the presence of a series of isolated basins that later coalesced into a single peat landform. This interpretation is consistent with previous conceptual models from studies in boreal regions. Ključne besede: peatland, ground penetrating radar, electrical resistivity tomography, peat probing, peat thickness Objavljeno v DiRROS: 07.07.2022; Ogledov: 1840; Prenosov: 876
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