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Povzetek: Novel nanoadsorbents demonstrate the potential to efficiently eliminate harmful substances, such as Hg2+, from the environment while preserving ecological balance. However, the search for environmentally-friendly nanomaterials as ideal adsorbents, as well as the development of suitable synthesis protocols, remains a challenge. This study presents an effective thermal-sonication technique for producing unique de novo tris-s-triazine carbon nitride nanosheets decorated with magnetite nanoparticles (M-g-CN). The structural integrity and chemical properties of the M-g-CN nanocomposite were extensively characterized using a battery of analytical instruments, including FTIR, SEM, TEM, XRD, XPS, AFM, Raman, and NMR. The obtained data, along with the analysis results, are discussed in detail. The novel synthesis method yields a high percentage (97.7%) of stable, highly selective, and reusable M-g-CN (40 mg mL−1). The resulting M-g-CN effectively binds Hg2+, with binding efficiencies of 96.0%, 97.5%, 98.2%, and 99.4% for Hg2+ concentrations of 50 pg mL−1 in marine, stream, precipitation, and ultra-pure matrices, respectively. Also, the magnetite-decorated particles can be easily retrieved using an applied magnetic field. This greener and scalable synthesis method does not require harsh chemicals, making it cost-effective, eco-friendly, and non-toxic compared to other technologies such as carbon filters, ion exchange resins, chemical precipitation, membrane filtration, electrochemical methods, and biological remediation. Overall, the synthesized M-g-CN exhibits wide-ranging potential applications, particularly as a green adsorbent in passive samplers or materials for remediation purposes.
Ključne besede: mercury, elimination, nanoadsorbents, nanocomposites
Objavljeno v DiRROS: 05.01.2026; Ogledov: 283; Prenosov: 108
Celotno besedilo (5,58 MB)
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Povzetek: The demand for alternative energy sources from non-recyclable waste materials will be a hot research topic in future industries. This interest is primarily due to the ability to harness energy from waste materials, the provision of localized power solutions, and the promotion of efficient power conversation. In this respect, Microbial Fuel Cells (MFC) represent new energy sources possessing unique qualities for many applications. MFC generates power by utilising exoelectrogens forming the biofilm on the surface of the anode. Since in the MFC, wastewater is primarily converted into protons and electrons at the anode surface, where biofilms typically develop, the anode becomes the most vital component. Consequently, significant research has been conducted on anode material to improve MFC performance. The present review focuses on different aspects of the MFC, including a comprehensive summary of the recent developments in the field of MFCs, including a state-of-the-art literature review based on a bibliometric analysis using keywords, a description of the mechanism and operational principle of MFC, applications and a summary of current research perspectives including the use of carbon nanotubes, graphene, graphitic carbon nitride, MXene, and their nanocomposites as anode materials with stable power density performance. Lastly, we present the challenges and future perspectives regarding the continued development of MFC anode materials, culminating in overall conclusions related to MFC research.
Ključne besede: microbial fuel cells, 2D nanomaterial, power density, nanocomposite, Anode
Objavljeno v DiRROS: 16.12.2025; Ogledov: 263; Prenosov: 162
Celotno besedilo (13,94 MB)
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