1. Light-assisted catalysis and the dynamic nature of surface species in the reverse water gas shift reaction over ▫$Cu/\gamma-Al_2O_3$▫Kristijan Lorber, Iztok Arčon, Matej Huš, Janez Zavašnik, Jordi Sancho-Parramon, Anže Prašnikar, Blaž Likozar, Nataša Novak Tušar, Petar Djinović, 2024, izvirni znanstveni članek Povzetek: The reverse water gas shift (RWGS) reaction converts CO2 and H2 into CO and water. We investigated Cu/γ-Al2O3 catalysts in both thermally driven and light-assisted RWGS reactions using visible light. When driven by combined visible light and thermal energy, the CO2 conversion rates were lower than in the dark. Light-assisted reactions showed an increase in the apparent activation energy from 68 to 87 kJ/mol, indicating that light disrupts the energetically favorable pathway active in the dark. A linear correlation between irradiance and decreasing reaction rate suggests a photon-driven phenomenon. In situ diffuse reflectance infrared Fourier transform spectroscopy and TD-DFT analyses revealed that catalyst illumination causes significant, partly irreversible surface dehydroxylation, highlighting the importance of OH groups in the most favorable RWGS pathway. This study offers a novel approach to manipulate surface species and control activity in the RWGS reaction.
Objavljeno v DiRROS: 19.12.2024; Ogledov: 310; Prenosov: 178
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2. Precise design and construction of NiO-Ni heterostructures for active hydrogen evolution photocatalysisKamal Khaja Mohaideen, Rekha Narayan, Selvakannan Periasamy, Sašo Gyergyek, Stefan Popovic, Nejc Hodnik, Hsin-Chia Ho, Petar Djinović, Blaž Likozar, 2024, izvirni znanstveni članek Objavljeno v DiRROS: 09.09.2024; Ogledov: 602; Prenosov: 4059
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3. Innovative microkinetic modelling-supported structure–activity analysis of Ni/ZSM-5 during vapor-phase hydrogenation of levulinic acidHue-Tong Vu, Žan Lavrič, Andrii Kostyniuk, Goran Dražić, Miha Grilc, Blaž Likozar, Nataša Zabukovec Logar, Petar Djinović, Nataša Novak Tušar, 2024, izvirni znanstveni članek Objavljeno v DiRROS: 26.07.2024; Ogledov: 609; Prenosov: 1040
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4. Winning combination of Cu and Fe oxide clusters with an alumina support for low-temperature catalytic oxidation of volatile organic compoundsTadej Žumbar, Iztok Arčon, Petar Djinović, Giuliana Aquilanti, Alenka Ristić, Goran Dražić, Janez Volavšek, Gregor Mali, Margarita Popova, Nataša Zabukovec Logar, Nataša Novak Tušar, Albin Pintar, Gregor Žerjav, 2023, izvirni znanstveni članek Objavljeno v DiRROS: 23.06.2023; Ogledov: 1137; Prenosov: 592
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5. Effects of Zr doping into ceria for the dry reforming of methane over ▫$Ni/CeZrO_2$▫ catalysts ein situ studies with XRD, XAFS, and AP-XPS : in situ studies with XRD, XAFS, and AP-XPSFeng Zhang, Zenghui Liu, Xiaobo Chen, Ning Rui, Luis E. Betancourt, Lili Lin, Wenqian Xu, Cheng-jun Sun, A. M. Milinda Abeykoon, José A. Rodriguez, Janvit Teržan, Kristijan Lorber, Petar Djinović, Sanjaya D. Senanayake, 2020, izvirni znanstveni članek Ključne besede: nickel, ceria, zirconia, ▫$CeZrO_2$▫ solid solution, XRD, XAFS, AP-XPS, dry reforming of methane
Objavljeno v DiRROS: 13.03.2023; Ogledov: 1199; Prenosov: 794
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