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1.
The corrosion resistance of dental Ti6Al4V with differing microstructures in oral environments
Mirjam Bajt Leban, Tadeja Kosec, Matjaž Finšgar, 2023, original scientific article

Abstract: The impact of the microstructural properties of a Ti6Al4V alloy on its electrochemical properties, as well as the effect of the α- and β-phases present within it, is still unclear. With the introduction of new, emerging technologies, such as selective laser melting and post heat treatments, the effect of the microstructure on an alloy's corrosion properties has become increasingly interesting from a scientific perspective. When these alloys are produced through different methods, despite an identical chemical composition they have diverse microstructures, and consequently display varying resistance to corrosion. In the present research study, Ti–6Al–4V alloy specimens produced by three different processes, leading to the formation of three different microstructures were investigated: heat treated specimen fabricated by selective laser melting, wrought and cast specimens. The impact of the microstructure of these alloys when immersed in artificial saliva was studied through the use of various electrochemical techniques, by microscopical examinations, and time-of-flight secondary ion mass spectrometry. Corrosion properties were investigated by the measurement of open circuit potential, linear polarization, and potentiodynamic curve measurements followed by microscopical examinations, and time-of-flight secondary ion mass spectrometry examination was conducted to reveal spatial distribution of alloying species on oxide film. It was found that the difference between specimens containing an α+β microstructure was small and not dependent on the aspect ratio of the β-phase, alloy grain size, and vanadium partitioning coefficient, but rather on the size, shape, and content of this phase.
Keywords: Ti6Al4V, dental alloy, microstructure, corrosion resistance, heat treatment, ToF-SIMS
Published in DiRROS: 26.10.2023; Views: 434; Downloads: 219
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2.
Corrosion characterization and ion release in SLM-manufactured and wrought Ti6Al4V alloy in an oral environment
Mirjam Bajt Leban, Tadeja Kosec, Matjaž Finšgar, 2022, original scientific article

Abstract: As-produced and heat-treated TiAlV samples were prepared by selective laser melting and compared to wrought samples of identical chemical composition. Microstructural, corrosion, and spectroscopic studies of additively manufactured samples in artificial saliva at 37 °C, with NaF and at pH 2.3 were as a novelty combined with metal ion release during 42 days immersion. In artificial saliva higher amount of ions was released on SLM specimen when compared to wrought alloy. The total amount of ions released from SLM specimen in AS containing NaF was 10-times higher than in AS, while in AS with lactic acid it was 100-times higher.
Keywords: Ti6Al4V, SLM, corrosion, ion release, XPS, ToF-SIMS
Published in DiRROS: 31.05.2023; Views: 297; Downloads: 248
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