20.500.12556/DiRROS-769 Effect of synthesis route of mesoporous zirconia based Ni catalysts on coke minimization in conversion of biogas to synthesis gas Mesoporous zirconia and nickel incorporated zirconia catalysts were prepared following different routes. Synthesis of mesoporous zirconia and Ni incorporated zirconia with very narrow pore size distributions and high surface area was achieved. Ni incorporated mesoporous zirconia materials showed high activity in carbon dioxide reforming of methane, performed at 600 °C. Coke formation during dry reforming was eliminated over the Ni incorporated zirconia catalyst prepared by the one-pot procedure, using Pluronic P123 as the surfactant. It was shown that Ni was very well distributed within this material with cluster sizes smaller than the detection limit of XRD. This catalyst also showed highly stable catalytic performance. However, the catalysts prepared by the impregnation method showed higher activity but much higher coke formation than the catalyst prepared by the one-pot route. Biogas syngas dry reforming mesoporous zirconia coke kemijsko inženirstvo bioplin sinteza konverzija true false true Angleški jezik Ni določen Članek v reviji 2015-02-12 12:19:59 2015-02-12 12:19:59 2022-08-10 03:32:37 0000-00-00 00:00:00 2015 0 0 Sodelavci: Sena Yasyerli, Nail Yasyerli, Gulsen Dogu, Timur Dogu, Petar Djinović, Albin Pintar; str. 3217-3228 iss. 8 Vol. 40 Mar. 2015 0000-00-00 NiDoloceno Objavljeno NiDoloceno 0000-00-00 0000-00-00 0000-00-00 66.02 0360-3199 10.1016/j.ijhydene.2015.01.023 5643034 3338511 http://ac.els-cdn.com/S0360319915000609/1-s2.0-S0360319915000609-main.pdf?_tid=5a67df8a-b038-11e4-9c50-00000aab0f02&acdnat=1423471861_afca97f85e53840632bfc3fd271df514 1 https://dirros.openscience.si/Dokument.php?lang=slv&id=821 Kemijski inštitut 0 0 0