20.500.12556/DiRROS-18842 The impact of urban rain on the changes of bare and artificially patinated bronze during 9-year exposure Atmospheric pollutants in the air form acid rain which interacts with bronze surfaces exposed in urban outdoor environment. In this study, different types of patinas on bronze were investigated during and after 9 years of exposure to urban environment in moderately polluted continental city. Natural bronze patina and artificial brown sulphide, green chloride, and green–blue nitrate patinas were investigated. Visual assessment was carried out at defined periods. After 9 years of exposure, an electrochemical study was performed to investigate the electrochemical activity of the patinas in artificial urban rain. Additionally, the patinas were characterised using a variety of techniques, including metallographic examination, scanning electron microscopy/energy dispersive X-ray spectroscopy, Raman spectroscopy, X-ray diffraction analysis, X-ray-photoelectron spectroscopy, and time-of-flight secondary ion mass spectrometry to analyse the surface morphology, chemical composition, and stratigraphic features of the patinas. Evolution of the patinas was shown to be a result of both, the composition of the acid rain and the hydrophobicity of the patinated surfaces. bronze bronze corrosion patina characterization bron urbano okolje korozija karakterizacija patine true false true Springer Angleški jezik Slovenski jezik © The Author(s) 2024 Neznano 2024-04-29 09:12:23 2024-04-29 09:21:03 2024-08-15 04:18:22 0000-00-00 00:00:00 2024 0 0 str. 31925-31941 Vol. 31 2024 0000-00-00 Zaloznikova Objavljeno NiDoloceno 0000-00-00 0000-00-00 2024-04-19 544.5/.6 1614-7499 oi.org/10.1007/s11356-024-33369-9 193395459 https://link.springer.com/article/10.1007/s11356-024-33369-9 1 d4febd40-05f7-11ef-a26d-001a4af901a5 https://dirros.openscience.si/Dokument.php?lang=slv&id=25787 RAZ_Kosec_Tadeja_2024.PDF RAZ_Kosec_Tadeja_2024.PDF 1 7AAAA130448B711110B258E6325F7799 311b2f3af39dcfc9c1dbd22e69ca033c8532ddc1cff585e06103c18d18b4a5bf cbc33a88-59f5-11ef-b487-001a4af901a5 https://dirros.openscience.si/Dokument.php?lang=slv&id=28278 http://dx.doi.org/oi.org/10.1007/s11356-024-33369-9 0 b3d5156a-05f8-11ef-a26d-001a4af901a5 https://dirros.openscience.si/Dokument.php?lang=slv&id=25788 RAZ_Kosec_Tadeja_2024.jpg RAZ_Kosec_Tadeja_2024.jpg 1 2786BA66CBD2E1EBFF6DD269692D4FA2 5a541ea3214bef3a76d313285cf003256376375e5ca0fd6de8cb064a14c74e50 f8c27f59-05f8-11ef-a26d-001a4af901a5 https://dirros.openscience.si/Dokument.php?lang=slv&id=25790 RAZ_Kosec_Tadeja_2024.docx RAZ_Kosec_Tadeja_2024.docx 1 732136E57012ED3ED7E91C02F9BE22F5 61f43e7fb9fdbd840ab8d1d40438710d8403c2afb091c5e835faf7db877c3ef4 ff830b09-05f8-11ef-a26d-001a4af901a5 https://dirros.openscience.si/Dokument.php?lang=slv&id=25791 Zavod za gradbeništvo Slovenije 0 0 0